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Last modified: January 26, 2018

Liouville's Theorem ------------------- Conider phase space of momentum, p, and position, q. p | . . | .(p,q) | | |_________q ^ y | point flow | ---> | | -- c -- | | | | |a b|Δy | | | | -- d -- | Δx | ------------------------- x The number of points in phase space moving in/out of the box is proportional to both the velocities at the boundaries and the length of the boundaries. x: vxaΔy - vxbΔy = (∂vx/∂x)ΔxΔy y: vydΔx - vycΔx = (∂vy/∂y)ΔxΔy Total change: [∂vx/∂x + ∂vy/∂y]ΔaΔy The flow in phase space is incompressible therefore the [] term must equal 0. This is the divergence of the velocity. In general Σi∂vi/∂xi = 0 or ∇.v = 0. Return to phase space. Replace vx with vq and vy with vp. Now from Hamilton's equations we get: . p = -∂H/∂q = vp . q = ∂H/∂p = vq Therefore, ∂vp/∂p = ∂/∂p(-∂H/∂q) and ∂vq/∂q = ∂/∂q(∂H/∂p) If we add these 2 equations we get 0. This means that the flow is incompressible. There is no convergence or divergence of trajectories. This is LIOUVILLE's THEOREM. . Consider a Lagrangian L = (1/2)mx2 . . Therefore px = ∂L/∂x = mx . . Now perform a transformation y = αx so that y/α = x and y/α = x. Now L becomes (assume m = 1): . . . L =(1/2)y22 and py = y/α2 = x/α = px/α Thus, Py = px/α So, if the q coordinate is stretched by α then the p coordinate must shrink by 1/α. In other words, the shape of an area can change but the area must be conserved under a coordinate transformation. The counting of the number of states available to a particle amounts to determining the available volume in phase space. One might think that for a continuous phase space, any finite volume would contain an infinite number of states. But the uncertainty principle tells us that we cannot simultaneously know both the position and momentum, so we cannot really say that a particle is at a mathematical point in phase space. So when we contemplate an element of "volume" in phase space du = dxdydzdpxdpydpz then the smallest "cell" in phase space which we can consider, is constrained by the uncertainty principle to be duminimum = h3 In the case of a chaotic system the phase space becomes fractal in nature. Unless you can measure this fractal with infinite precision then its area will be larger than the original one. This is referred to as COARSE GRAINING.